不清楚为什么需要正则表达式--检查值肯定是：

between 1 and 59 or between 61 and 99

更容易吗
如果必须使用regex，PL/SQL对此有广泛的支持。

begin
  for vals in 59 .. 61 loop
    if regexp_like ( vals, '(00)|(60)' ) then
      dbms_output.put_line ( vals || ' = fail' );
    else
      dbms_output.put_line ( vals || ' = pass' );
    end if;
  end loop;
end;

59 = pass
60 = fail
61 = pass

答案似乎是：

^(?!.*00|.*60).\d$

这将否定特定的字符组（00或60），并允许其他数字。
我无法编辑我的问题来解释以下内容;
我们在表中存储一个正则表达式，用于验证每个字段的传入字符串，而不是硬编码每个传入字段的验证。每行有超过400个传入数据元素。

--Assumption: vals is 2 digit 
--Having two comparisons gives some flexibility in adjusting if necessary.
-- 'i' optional meaning ignore case sensitivity
where
         regexp_like(vals,'^[0-9][0-9]$','i') --Set of Numbers to INCLUDE
and  NOT regexp_like(vals,'^[0,6][0]$','i')     --Set of Numbers to EXCLUDE

with set_of_numbers as
(
select '00' as valid_yn from dual union all
select '01' as valid_yn from dual union all
select '02' as valid_yn from dual union all
select '59' as valid_yn from dual union all
select '60' as valid_yn from dual union all
select '61' as valid_yn from dual union all
select '99' as valid_yn from dual)
select valid_yn 
from set_of_numbers
where 
         regexp_like(valid_yn,'^[0-9][0-9]$','i') --Set of Numbers to INCLUDE
and  NOT regexp_like(valid_yn,'^[0,6][0]$','i')  --Set of Numbers to EXCLUDE
;