来自文档：https://pypi.org/project/pytesseract/
这表明您缺少BGR到RGB的转换，即

import cv2

img_cv = cv2.imread(r'/<path_to_image>/digits.png')

# By default OpenCV stores images in BGR format and since pytesseract assumes RGB format,
# we need to convert from BGR to RGB format/mode:
img_rgb = cv2.cvtColor(img_cv, cv2.COLOR_BGR2RGB)
print(pytesseract.image_to_string(img_rgb))
# OR
img_rgb = Image.frombytes('RGB', img_cv.shape[:2], img_cv, 'raw', 'BGR', 0, 0)
print(pytesseract.image_to_string(img_rgb))